Prep the pan and oven: Heat the oven to 350°F (175°C). Grease a 9x5-inch loaf pan and line it with a parchment sling for easy removal.
Grate the zucchini: Use the large holes of a box grater. Place the grated zucchini in a clean kitchen towel and gently squeeze out excess moisture.
You want it damp, not dripping.
Mix dry ingredients: In a medium bowl, whisk the flour, cocoa powder, baking soda, baking powder, salt, and espresso powder until no lumps remain.
Whisk wet ingredients: In a large bowl, whisk the eggs, granulated sugar, and brown sugar until smooth. Whisk in the oil, vanilla, and yogurt until well combined.
Combine batter: Add the dry ingredients to the wet and stir with a spatula just until a few streaks of flour remain. Fold in the zucchini and chocolate chips until evenly distributed.
Do not overmix.
Fill the pan: Scrape the batter into the prepared loaf pan and smooth the top. Sprinkle a small handful of chocolate chips over the surface for a glossy finish.
Bake: Bake for 55–65 minutes, or until a toothpick inserted near the center comes out with a few moist crumbs. If the top is browning too quickly, tent it loosely with foil during the last 10–15 minutes.
Cool: Let the loaf cool in the pan for 15 minutes, then lift it out using the parchment and transfer to a wire rack.
Cool completely before slicing for the cleanest cuts.
Slice and serve: Use a sharp serrated knife. Enjoy slightly warm or at room temperature.